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《Journal of the European Ceramic Society》2019,39(15):4554-4564
To investigate the formation mechanism of the dendrites glass-ceramics and the effect of TaB2 modifier on the oxidation-inhibition ability of Si-based coatings in aerobic environment with broad temperature region for carbon materials, the Si-based coatings modified with different TaB2 content were fabricated by the liquid phase sintering method. The fabricated coatings and its corresponding composite powders were investigated in dynamic TG aerobic environments up to 1500 ℃. The initial oxidation temperatures of Si-based coatings modified with TaB2 powders are almost completely suppressed to 800 ℃. With the increase of TaB2 phase content, the relative oxygen permeability of the Si-based coatings is significantly reduced, which can be interpreted as the generation of liquid boride, silicide and Ta-Si-B-O compound glass ceramics those can improve the stability of the coating. The formation mechanism of the dendrites glass-ceramics was illustrated. 相似文献
94.
Kai Sun Wei Xiao Sheng Ye Nikolaos Kalfagiannis Kian Shen Kiang C. H. de Groot Otto L. Muskens 《Advanced materials (Deerfield Beach, Fla.)》2020,32(25):2001534
New methods for achieving high-quality conducting oxide metasurfaces are of great importance for a range of emerging applications from infrared thermal control coatings to epsilon-near-zero nonlinear optics. This work demonstrates the viability of plasma patterning as a technique to selectively and locally modulate the carrier density in planar Al-doped ZnO (AZO) metasurfaces without any associated topographical surface profile. This technique stands in strong contrast to conventional physical patterning which results in nonplanar textured surfaces. The approach can open up a new route to form novel photonic devices with planar metasurfaces, for example, antireflective coatings and multi-layer devices. To demonstrate the performance of the carrier-modulated AZO metasurfaces, two types of devices are realized using the demonstrated plasma patterning. A metasurface optical solar reflector is shown to produce infrared emissivity equivalent to a conventional etched design. Second, a multiband metasurface is achieved by integrating a Au visible-range metasurface on top of the planar AZO infrared metasurface. Independent control of spectral bands without significant cross-talk between infrared and visible functionalities is achieved. Local carrier tuning of conducting oxide films offers a conceptually new approach for oxide-based photonics and nanoelectronics and opens up new routes for integrated planar metasurfaces in optical technology. 相似文献
95.
目的研究纳米氧化锌/低密度聚乙烯膜(low density polyethylene film,LDPE)中锌(Zn)向食品的迁移行为,探究其迁移规律。方法选取2种食品模拟物(3%乙酸及超纯水)及真实食品(食用白醋及瓶装水),在3种不同实验温度下(70、40及20℃),研究锌向食品模拟物的迁移规律。采用扫描电子显微镜(scanning electron microscope,SEM)和原子力显微镜(atomic force microscope,AFM)表征纳米ZnO/LDPE膜的表面形貌。结果锌向酸性模拟物中的迁移率远远大于水性模拟物中的迁移率,其中锌向酸性模拟物中的最大迁移率分别为22.7%,20.3%及18.6%(ZL-1,ZL-2及ZL-2#),向水性模拟物中的最大迁移率分别为9.9%,5.7%及4.9%(ZL-1,ZL-2及ZL-2#);锌向酸性食品的迁移量(1.59~5.03 mg/g)同样高于向水性食品的迁移量(2.98~24.60μg/g);随着纳米ZnO的初始含量变大迁移率变小;而偶联剂的加入对锌的迁移有一定的抑制作用。随着纳米ZnO浓度的增加,在薄膜中观察到纳米ZnO的不规则形貌。结论纳米ZnO/LDPE膜不适合在高温下包装食物,且其在酸性食品中的安全隐患高于水性食品。 相似文献
96.
Shuhui YANG 《等离子体科学和技术》2020,22(12):125401
Cold atmospheric plasma shows a satisfactory ability to inactivate bacterial biofilms that are difficult to remove using conventional methods in some cases. However, the researches on the inactivation mechanism are not quite sufficient. Poly-β-1–6-N-acetylglucosamine (PNAG), which is one of the important components in some biofilms, was used as the research subject, and the related mechanism of action triggered by different concentrations of the OH in plasma was studied using reactive molecular dynamics simulations. The results showed that OH radicals could not only trigger the hydrogen abstraction reaction leading to cleavage of the PNAG molecular structure, but undergo an OH addition reaction with PNAG molecules. New reaction pathways appeared in the simulations as the OH concentration increased, but the reaction efficiency first increased and then decreased. The simulation study in this paper could, to some extent, help elucidate the microscopic mechanism of the interaction between OH radicals in plasma and bacterial biofilms at the atomic level. 相似文献
97.
文章分析了3a马尔康国家基准气候站AG2.0型超声波蒸发传感器观测数据,结果表明:蒸发传感器遇低温结冰时段自动观测数据偏大。对1d中部分时间段内蒸发水结冰、融化以及冬季全天结冰期很短的观测数据进行了分析,分析认为数据偏大主要是因为蒸发桶和测量筒的材料物理性质以及测量的水体面积不同。最后提出了数据记录处理建议。 相似文献
98.
Yaya Wang Wei Gao 《Energy Sources, Part A: Recovery, Utilization, and Environmental Effects》2018,40(8):987-993
Fuel quality, especially biodiesel, is highly dependent on its water content, and the major sources of water in the fuel relate to the transportation, production, and storage processes. In this present contribution, the multilayer perceptron artificial neural network (MLP-ANN) was applied to predict the water content of biodiesel and diesel blend in terms of temperature and composition. The proposed algorithm was trained and tested by utilizing 400 experimental data points which were extracted from the literature. Based on the results, the MLP-ANN model has great ability to estimate the water content of biodiesel and diesel blend. The R-squared (R2), root mean square error, average absolute relative deviation, and a?bsolute deviation parameters for the total data set are obtained, respectively, as 0.99784, 123919.1172, 3.3632, and 1.17%, which indicate the effective performance suggested by ANN. As the computational study is cheaper and easier than the experimental study, the developed software could be considered as an alternative for laboratory study, and the environmental effect of biodiesel and produced undesired product after biodiesel combustion which is directly related to the water content of biodiesel is estimable with the information released in this study. 相似文献
99.
100.
为了提高光面爆破成型质量,提出了一种低能量密度炸药连续装药光面爆破技术,利用LS DYNA进行数值模拟,对比2#岩石乳化炸药间隔装药和低能量密度炸药连续装药的应力场,然后将此技术用于长九(神山)灰岩矿四号隧洞控制爆破和露天边坡光面爆破。结果表明:2#岩石乳化炸药间隔装药模型中,装药段与非装药段测点应力峰值相差很大;而在低能量密度炸药连续装药模型中,沿炮孔轴向相同爆心距的测点应力峰值保持一致;使用低能量密度炸药进行连续装药,能够避免装药段的过度破坏和非装药段的欠挖,提高残孔率,且省去了导爆索捆绑时间,提高周边孔装药效率,节省了爆破成本。 相似文献